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SAFETY DATA SHEET

Section 1:  Identification

Product Name:

PRECIPITATION SOLUTION #3

Synonyms:

Sodium Hydroxide Solution

Recommended Use:

Laboratory chemical

Restrictions on Use:

Do not ingest or allow to come in contact with skin or eyes

Company Identification:

FULLER ENGINEERING INC.

 

975 E. Orangefair Lane, Anaheim, Ca 92801

Non-emergency Assistance:

714-502-0700

Emergency 24 Hour Assistance:

ChemTel 1-800-255-3924 (Contract Number MIS8057228)

 

Section 2:  Hazard(s) Identification

Hazard Classification:

Corrosive to metals

Category 1

 

Skin corrosion/irritation

Category 1

 

Serious eye damage/Eye irritation

Category 1

 

Specific target organ toxicity(single exposure)

Category 3 (respiratory system)

Signal Word:

Danger

Hazard Statement(s):

May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation.

Pictograms:

       

Precautionary statement(s):

Do not breath dust/fumes/gas/mist/vapors/spray. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection.  Keep only in closed original container. IF SWALLOWED: Rinse with plenty of water. Do not induce vomiting. Call a Poison Center or doctor/physician if you feel unwell. IF ON SKIN(or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.  Immediately call a doctor/physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Store in corrosive resistant polypropylene container with a resistant inliner. Dispose of contents and container in accordance with all local, regional, national, and international regulations.

 

Section 3: Composition/Information on Ingredients

Chemical Name

Synonyms

CAS No.

Weight %

Sodium Hydroxide

Liquid caustic solution

1310-73-2

*

*The specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.

 

Section 4: First-Aid Measures

Emergency and First Aid Procedures:

Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.

If in eyes:

Flush eyes with plenty of water for at least 15 minutes.  Remove contact lenses if able to do so.  Get medical attention/advice.

If on skin or clothing:

Flush skin with plenty of water for at least 15 minutes and wash with soap and water.  Remove contaminated clothing and shoes.  If irritation persists, consult a physician.

If inhaled:

Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Immediate medical attention is required.

If swallowed:

Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a doctor.

         

 

Section 5: Fire-Fighting Measures

Flash Point:

N/A

Flammability:

Non flammable  

Products of combustion:

Corrosive Material. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Keep product and empty container away from heat and sources of ignition. Sodium oxides Carbon monoxide (CO) Carbon dioxide (CO2)

Extinguishing Media:

Use water-spray, dry chemical, or foam. Tailor extinguishing media to surrounding fire.

Protective equipment and precautions for firefighters:

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Section 6:  Accidental Release Measures

Personal precautions:

Wear self-contained breathing apparatus and protective suit. Evacuate personnel to safe areas. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing.

Environmental Precautions:

If safe to do so, avoid the dispersal of spilled material and contact with soil, waterways, drains, and sewers.  Inform the relevant authorities if the product has caused environmental pollution. Collect spillage.

Containment and cleanup:

If safe to do so, stop the leak/spill and dike the area. Ventilate the area if spilled in confined space or other poorly ventilated areas. Absorb spill with inert material (e.g. vermiculite, sand or earth). Collect  material in a clean container for disposal according to local regulations. Spilled liquid and dried film are slippery. Use care to avoid falls.

     

 

Section 7:  Handling and Storage

Safe handling:

Use caution while handling - material is corrosive.  Use appropriate personal protective equipment.  Handle in a well-ventilated area.  Handle in a manner consistent with good industrial/manufacturing techniques and practices.  Wash hands thoroughly with soap and water after use.  Remove contaminated clothing and protective equipment before entering eating area.  Avoid contact with eyes, skin, and clothing.

Safe storage:

Keep containers tightly closed in a cool, dry, well-ventilated place away from direct sunlight.  Containers which are opened must be carefully resealed and kept upright to prevent leakage.  Store away from incompatible materials.

 

Section 8:  Exposure Controls/Personal Protection

Exposure limits:

OSHA PEL (Permissible Exposure Limit):  (Vacated) Ceiling: 2 mg/m3 TWA: 2 mg/m3

 

ACGIH (American Conference of Governmental Industrial Hygienists) TLV (Short Term):  Ceiling: 2 mg/m3

 

NIOSH REL (Short Term):  IDLH: 10 mg/m3 Ceiling: 2 mg/m3

Engineering controls:

Use in well-ventilated area. Ensure water is available nearby. Provide readily accessible eye wash stations and safety showers.

Personal protective equipment:

Chemical resistant gloves, protective clothing, chemical safety glasses, face protection. Respirator protection is not normally required.

 

Section 9:  Physical and Chemical Properties

Appearance:

Clear liquid

Solubility:

Soluble

Upper/lower flammability or explosive limits:

N/A

Partition coefficient: n-octanol/water:

unknown

Odor:

None

Flash point:

N/A

Vapor pressure:

unknown

Evaporation rate:

unknown

Odor threshold:

unknown

Flammability (solid, gas):

N/A

Melting point/freezing point:

>12C/53.6F

Decomposition temperature:

unknown

pH:

 >11

Auto-ignition temperature:

N/A

Relative density (Specific Gravity):

unknown

Boiling point and boiling range:

>145C/293F

Vapor density:

unknown

Viscosity:

unknown

 

Section 10:  Stability and Reactivity

Stability:

Stable under recommended storage conditions.

Conditions to avoid:

Acids, Organic materials, Metals, Water, excess hear, exposure to air or water. Corrosive to metals.

Hazardous decomposition products:

Sodium oxides, Carbon monoxide (CO), Carbon dioxide (CO2)

Hazardous polymerizations:

Hazardous polymerization does not occur.

 

Section 11:  Toxicological Information

Routes of exposure:

Inhalation, ingestion, skin and eye contact

Acute Toxicity:

Oral Toxicity (LD50), oral, rabbit: 1350 mg/kg   Dermal Toxicity (LD50), oral, rabbit: not listed

Effects from short- and long-term exposure:

Inhalation may cause respiratory irritation.  Avoid contact which can cause serious irritation, redness, or severe burns. Pre-existing skin conditions may be aggravated by prolonged or repeated exposure. May be harmful if swallowed.  Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.

Carcinogenicity:

No component in this product is identified as carcinogenic by IARC, NTP, ACGIH, or OSHA.

Mutagenicity:

No known significant effects or critical hazards.

 

Section 12: Ecological Information

Aquatic toxicity:

LC50 (Freshwater Fish, 96 h): 45.4 mg/l 

Persistence and degradability:

Soluble in water Persistence is unlikely based on information available.

Bioaccumulation potential:

No information available.

Mobility in soil:

Will likely be mobile in the environment due to its water solubility.

 

Section 13: Disposal Considerations

The generation of waste should be avoided or minimized wherever possible.  Material and contaminated packaging should be disposed of in accordance with all local, state, and federal regulations(regulations vary by region). Avoid release into soil, sewers, drains, and waterways.

 

Section 14: Transport Information

DOT:

Sodium Hydroxide Solution, 8, UN 1824 PG II, RQ = 1000 lbs

 

Other Information:

SDS revision date:

5/19/2016

The statements contained herein are offered as informational data only and are believed to be correct.  However, this product should be handled by persons having related technical skills, and at their own discretion and risk.  Since seller has no control over the use of this product, no warranty, expressed or implied, is made and seller assumes no liability in connection with any use of this information or from contact and/or handling of this product.

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Last modified: May 26, 2016